Ionic hydrogenation of C-20, 22-ketene dithioacetal: stereoselective synthesis of steroidal C (20R) aldehydes

Homologation of 16-dehydropregnenolone acetate leads to excellent stereocontrolled synthesis of unnatural C (20R) aldehydes and through compound .

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2004-10 (19), p.2194-2195
Main Authors: Shingate, Bapurao B, Hazra, Braja G, Pore, Vandana S, Gonnade, Rajesh G, Bhadbhade, Mohan M
Format: Article
Language:English
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Description
Summary:Homologation of 16-dehydropregnenolone acetate leads to excellent stereocontrolled synthesis of unnatural C (20R) aldehydes and through compound .
ISSN:1359-7345
1364-548X
DOI:10.1039/b407952c