Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state

We present low-energy velocity map photoelectron imaging results for nitromethane anions. The photoelectron spectrum is interpreted with the aid of ab initio theory and Franck-Condon factor calculations. We obtain a new value for the adiabatic electron affinity of nitromethane of (172+/-6) meV and o...

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Published in:The Journal of chemical physics 2009-02, Vol.130 (7), p.074307-074307
Main Authors: Adams, Christopher L, Schneider, Holger, Ervin, Kent M, Weber, J Mathias
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Language:English
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description We present low-energy velocity map photoelectron imaging results for nitromethane anions. The photoelectron spectrum is interpreted with the aid of ab initio theory and Franck-Condon factor calculations. We obtain a new value for the adiabatic electron affinity of nitromethane of (172+/-6) meV and observe the dipole-bound state of nitromethane. The photoelectron angular distributions of the observed features are discussed in the context of threshold laws for photodetachment.
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title Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state
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