Supramolecular complex composed of a covalently linked zinc porphyrin dimer and fulleropyrrolidine bearing two axially coordinating pyridine entities

A zinc porphyrin dimer-fullerene supramolecular complex with a large association constant is assembled; efficient intramolecular photoinduced electron transfer from the singlet excited state of zinc porphyrin to the fullerene is observed.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2004-10 (20), p.2276-2277
Main Authors: D'Souza, Francis, Gadde, Suresh, Zandler, Melvin E, Itou, Mitsunari, Araki, Yasuyuki, Ito, Osamu
Format: Article
Language:English
Subjects:
Electrons
Fullerenes - chemistry
Models, Molecular
Photochemistry
Porphyrins - chemistry
Pyridines - chemical synthesis
Spectrometry, Fluorescence
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Description
Summary:A zinc porphyrin dimer-fullerene supramolecular complex with a large association constant is assembled; efficient intramolecular photoinduced electron transfer from the singlet excited state of zinc porphyrin to the fullerene is observed.
ISSN:1359-7345
1364-548X
DOI:10.1039/b407985j