Highly Versatile Organostibine Mediators for Living Radical Polymerization

A new versatile method for conducting living radical polymerization has been developed in which organostibines induce consecutive group-transfer radical reactions with alkenes. The method has been successfully applied, for the first time, to the controlled polymerization of both conjugated and uncon...

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Published in:Journal of the American Chemical Society 2004-11, Vol.126 (43), p.13908-13909
Main Authors: Yamago, Shigeru, Ray, Biswajit, Iida, Kazunori, Yoshida, Jun-ichi, Tada, Tomofumi, Yoshizawa, Kazunari, Kwak, Yungwan, Goto, Atsushi, Fukuda, Takeshi
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Language:English
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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cited_by cdi_FETCH-LOGICAL-a423t-481c1d481abc61d1036c634d1d4725142ac6d416489413dd4a29fe40b4f032573
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container_end_page 13909
container_issue 43
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container_title Journal of the American Chemical Society
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creator Yamago, Shigeru
Ray, Biswajit
Iida, Kazunori
Yoshida, Jun-ichi
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Goto, Atsushi
Fukuda, Takeshi
description A new versatile method for conducting living radical polymerization has been developed in which organostibines induce consecutive group-transfer radical reactions with alkenes. The method has been successfully applied, for the first time, to the controlled polymerization of both conjugated and unconjugated vinyl monomers, and the desired polymers with predetermined molecular weight and low polydispersity index were obtained in excellent yields. This characteristic feature of this method is exemplified in the first synthesis of block copolymers composed of conjugated and unconjugated monomers, which would be of great importance as functional smart organic nanomaterials.
doi_str_mv 10.1021/ja044787v
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Highly Versatile Organostibine Mediators for Living Radical Polymerization
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