Structurally diverse Rh(I) and Mn(I) complexes derived from the new ambidentate indene ligand, (1-[iPr2P(S)]-2-[NMe2])C9H6

A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a kappa2-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in kappa2-[C,S] and eta5 modes, respectively.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2004-11 (21), p.2446-2447
Main Authors: Wechsler, Dominik, McDonald, Robert, Ferguson, Michael J, Stradiotto, Mark
Format: Article
Language:English
Subjects:
Crystallography, X-Ray
Indenes - chemistry
Ligands
Manganese - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Rhodium - chemistry
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Description
Summary:A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a kappa2-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in kappa2-[C,S] and eta5 modes, respectively.
ISSN:1359-7345
1364-548X
DOI:10.1039/b410328a