Applications of the parahydrogen phenomenon in inorganic chemistry

The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that arise from the physical constraints of the detection method. An overview is presented of how chemical reactions can be studied using parahydrogen assisted NMR spectroscopy where detected signal...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2004-09 (17), p.2601-2609
Main Authors: Blazina, Damir, Duckett, Simon B, Dunne, John P, Godard, Cyril
Format: Article
Language:English
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Summary:The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that arise from the physical constraints of the detection method. An overview is presented of how chemical reactions can be studied using parahydrogen assisted NMR spectroscopy where detected signal strengths can exceed those normally seen by factors of over 28,000.
ISSN:1477-9226
1477-9234
DOI:10.1039/b409606a