Adsorption of zinc on bed sediment of River Hindon: adsorption models and kinetics

• Published in: Journal of hazardous materials 2004-10, Vol.114 (1), p.231-239
• Main Authors: Jain, C.K., Singhal, D.C., Sharma, M.K.
• Format: Article
• Language: English
• Subjects: Adsorption; Adsorption models; Applied sciences; Continental surface waters; Diffusion; Exact sciences and technology; Geologic Sediments - chemistry; Hydrogen-Ion Concentration; India; Kinetics; Models, Chemical; Natural water pollution; Pollution; Sediments; Thermodynamics; Water treatment and pollution; Zinc; Zinc - chemistry
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2004.09.001

The paper presents a study of zinc adsorption using the experimental data on bed sediments of River Hindon in western Uttar Pradesh (India). The effect of various operating variables, viz., initial concentration, solution pH, sediment dose, contact time, and particle size, have been studied. The optimum contact time needed to reach equilibrium was of the order of 60 min and was independent of initial concentration of zinc ions. The extent of adsorption increased with an increase of pH. Furthermore the adsorption of zinc increases with increasing adsorbent doses and decreases with the adsorbent particle size. The content of iron, manganese and organic matter in various fraction of sediment decreases with increasing particle size indicating the possibility of the two geochemical phases to act as the active support material for the adsorption of zinc ions. The adsorption data follows both Langmuir and Freundlich adsorption models. Isotherms were used to determine thermodynamic parameters, viz., free energy change, enthalpy change and entropy change. The negative values of free energy change indicate spontaneous nature of the adsorption while positive values of enthalpy change suggest the endothermic nature of the adsorption of zinc on bed sediment of the River Hindon. The positive values of entropy change indicate randomness at the solid/solution interface.