Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

Air-stable Lewis acidic micro2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2009-01 (13), p.1679-1681
Main Authors: Qiu, Renhua, Xu, Xinhua, Li, Yinhui, Zhang, Guoping, Shao, Lingling, An, Delie, Yin, Shuangfeng
Format: Article
Language:English
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Summary:Air-stable Lewis acidic micro2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.
ISSN:1359-7345
1364-548X
DOI:10.1039/b821366f