On the dissociation of I2 by O2(a1Delta): Pathways involving the excited species I2(A'3Pi2u,A3Pi(1u)), I2(X1sigma,upsilon), and O2(a1Delta,upsilon)

• Published in: The Journal of chemical physics 2009-03, Vol.130 (10), p.104306-104306
• Main Authors: Azyazov, V N, Pichugin, S Yu, Heaven, Michael C
• Format: Article
• Language: English
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.3081454

Kinetic studies were carried out to explore the role of the excited species I(2)(A(') (3)Pi(2u),A (3)Pi(1u)), I(2)(X (1) summation operator,upsilon), and O(2)(a (1)Delta,upsilon) in the dissociation of I(2) by singlet oxygen. A flow tube apparatus that utilized a chemical singlet oxygen generator was used to measure the I(2) dissociation rate in O(2)(a (1)Delta)/I(2) mixtures. Vibrationally excited I(2)(X) is thought to be a significant intermediate in the dissociation process. Excitation probabilities (gamma(upsilon)) for population of the upsilonth I(2)(X) vibrational level in the reaction I(2)(X)+I((2)P(1/2))-->I(2)(X,upsilon>10)+I((2)P(3/2)) were estimated based on a comparison of calculated populations with experimentally determined values. Satisfactory agreement with the experimental data [Barnault et al., J. Phys. IV 1, C7/647 (1991)] was achieved for total excitation probabilities partitioned in two ranges, such that Gamma(25