Formation of a Thermally Stable, Porous Coordination Network via a Crystalline-to-Amorphous-to-Crystalline Phase Transition

A porous coordination network was cleanly obtained after a crystalline-to-amorphous-to-crystalline phase transition, and the crystal structure was unambiguously solved by ab initio powder X-ray diffraction. After the solid-state phase transition, the porous structure was remarkably stable up to 673...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2009-03, Vol.131 (11), p.3860-3861
Main Authors: Ohara, Kazuaki, Martí-Rujas, Javier, Haneda, Tsuyoshi, Kawano, Masaki, Hashizume, Daisuke, Izumi, Fujio, Fujita, Makoto
Format: Article
Language:English
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Summary:A porous coordination network was cleanly obtained after a crystalline-to-amorphous-to-crystalline phase transition, and the crystal structure was unambiguously solved by ab initio powder X-ray diffraction. After the solid-state phase transition, the porous structure was remarkably stable up to 673 K and capable of reabsorbing various guest molecules, such as aromatic solvents and I2.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja9005145