Saddle-shaped six-coordinate iron(iii) porphyrin complex with unusual intermediate-spin electronic structure

An unusual intermediate-spin electronic structure d(xz,yz)(3)d(xy)(1)d(z(2))(1) has been assigned to the six-coordinate saddled [Fe(OETPP)(4-CNPy)(2)](+) complex through density functional calculation and NMR spectroscopy analysis.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2009-01 (16), p.2180-2182
Main Authors: Cheng, Ru-Jen, Chao, Chia-Wei, Han, Ya-Ping, Chen, Yen-Chou, Ting, Chiao-Han
Format: Article
Language:English
Subjects:
Ferric Compounds - chemistry
Models, Molecular
Molecular Structure
Porphyrins - chemistry
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Summary:An unusual intermediate-spin electronic structure d(xz,yz)(3)d(xy)(1)d(z(2))(1) has been assigned to the six-coordinate saddled [Fe(OETPP)(4-CNPy)(2)](+) complex through density functional calculation and NMR spectroscopy analysis.
ISSN:1359-7345
1364-548X
DOI:10.1039/b820443h