A Molybdenum Crown Cluster Forms Discrete Inorganic-Organic Nanocomposites with Metalloporphyrins

Filled doughnuts: Molybdenum crown cluster MC accommodates up to three molecules of aminophenyl‐substituted metalloporphyrins through hydrogen‐bonding interactions, to form discrete inorganic–organic nanocomposite materials (see picture; blue polyhedra=MC, space‐filling model=metalloporphyrin). Ultr...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2004-11, Vol.43 (46), p.6327-6331
Main Authors: Tsuda, Akihiko, Hirahara, Eri, Kim, Yeong-Sang, Tanaka, Hiroyuki, Kawai, Tomoji, Aida, Takuzo
Format: Article
Language:English
Subjects:
inorganic/organic nanocomposites
polyoxomolybdates
porphyrinoids
scanning probe microscopy
supramolecular chemistry
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Summary:Filled doughnuts: Molybdenum crown cluster MC accommodates up to three molecules of aminophenyl‐substituted metalloporphyrins through hydrogen‐bonding interactions, to form discrete inorganic–organic nanocomposite materials (see picture; blue polyhedra=MC, space‐filling model=metalloporphyrin). Ultrahigh‐vacuum scanning tunneling microscopy, in conjunction with scanning tunneling spectroscopy, at 80 K confirms the formation of the inclusion complex.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460990