Universal spectrochemical series of six-coordinate octahedral metal complexes for modifying the ligand field splitting

We studied a novel universal spectrochemical series of six-coordinated octahedral 3d transition metal complexes, which can be used for any combination of central metal atom and ligand molecules. A two dimensional spectrochemical series could be used to estimate the ligand field splitting energy of n...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (4), p.680-687
Main Authors: Ishii, Tomohiko, Tsuboi, Shino, Sakane, Genta, Yamashita, Masahiro, Breedlove, Brian K
Format: Article
Language:English
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Summary:We studied a novel universal spectrochemical series of six-coordinated octahedral 3d transition metal complexes, which can be used for any combination of central metal atom and ligand molecules. A two dimensional spectrochemical series could be used to estimate the ligand field splitting energy of not only known compounds but also the unknown compounds. Therefore, it should be possible to control the physical properties, such as the electronic and magnetic properties and the optical phenomena of octahedral transition metal complexes by modifying the ligand field splitting.
ISSN:1477-9226
1477-9234
DOI:10.1039/b810590a