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Supramolecular Crystalline Sheets with Ordered Nanopore Arrays from Self-Assembly of Rigid-Rod Building Blocks

Self‐assembly of rod‐coil molecules with an ester linkage gave a honeycomblike supramolecular structure with 3D hexagonal symmetry. Hydrolysis of the ester linkages and removal of the coil segments (light blue) from the perforated lamellar structure afforded crystalline sheets (dark blue) with in‐pl...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2004-12, Vol.43 (47), p.6465-6468
Main Authors: Lee, Myongsoo, Park, Myoung-Hwan, Oh, Nam-Keun, Zin, Wang-Cheol, Jung, Hee-Tae, Yoon, Dong Ki
Format: Article
Language:English
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Summary:Self‐assembly of rod‐coil molecules with an ester linkage gave a honeycomblike supramolecular structure with 3D hexagonal symmetry. Hydrolysis of the ester linkages and removal of the coil segments (light blue) from the perforated lamellar structure afforded crystalline sheets (dark blue) with in‐plane arrays of nanopores whose hydrophobic interiors entrap nonpolar molecules.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460378