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Supramolecular Crystalline Sheets with Ordered Nanopore Arrays from Self-Assembly of Rigid-Rod Building Blocks
Self‐assembly of rod‐coil molecules with an ester linkage gave a honeycomblike supramolecular structure with 3D hexagonal symmetry. Hydrolysis of the ester linkages and removal of the coil segments (light blue) from the perforated lamellar structure afforded crystalline sheets (dark blue) with in‐pl...
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Published in: | Angewandte Chemie International Edition 2004-12, Vol.43 (47), p.6465-6468 |
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container_end_page | 6468 |
container_issue | 47 |
container_start_page | 6465 |
container_title | Angewandte Chemie International Edition |
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creator | Lee, Myongsoo Park, Myoung-Hwan Oh, Nam-Keun Zin, Wang-Cheol Jung, Hee-Tae Yoon, Dong Ki |
description | Self‐assembly of rod‐coil molecules with an ester linkage gave a honeycomblike supramolecular structure with 3D hexagonal symmetry. Hydrolysis of the ester linkages and removal of the coil segments (light blue) from the perforated lamellar structure afforded crystalline sheets (dark blue) with in‐plane arrays of nanopores whose hydrophobic interiors entrap nonpolar molecules. |
doi_str_mv | 10.1002/anie.200460378 |
format | article |
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source | Wiley-Blackwell Read & Publish Collection |
subjects | nanostructures rod-coil molecules self-assembly supramolecular chemistry |
title | Supramolecular Crystalline Sheets with Ordered Nanopore Arrays from Self-Assembly of Rigid-Rod Building Blocks |
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