Preparation of 1-p-Halophenyl and 1-p-Biphenylyl Substituted Monocarbadodecaborate Anions [closo-1-Ar−CB11H11]- by Insertion of Arylhalocarbenes into [nido-B11H14]

In the presence of a strong base, benzal chloride (C6H5CHCl2) and its p-substituted derivatives react with [nido-B11H14]- to yield [closo-1-p-X−C6H4−CB11H11]- (X = H, F, Cl, Br, I, Ph), presumably by insertion of an arylhalocarbene and oxidation. On a 1-g scale, the yields are 30−40%, except in the...

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Published in:Inorganic chemistry 2004-12, Vol.43 (25), p.8158-8161
Main Authors: Körbe, Stefanie, Sowers, Damian B, Franken, Andreas, Michl, Josef
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cited_by cdi_FETCH-LOGICAL-a313t-a29645998e452b9196fe3826da20867c998f9a6d3230d0ccee271d92a4476a6e3
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description In the presence of a strong base, benzal chloride (C6H5CHCl2) and its p-substituted derivatives react with [nido-B11H14]- to yield [closo-1-p-X−C6H4−CB11H11]- (X = H, F, Cl, Br, I, Ph), presumably by insertion of an arylhalocarbene and oxidation. On a 1-g scale, the yields are 30−40%, except in the case of p-iodobenzal chloride, which yields only 12% of the insertion product.
doi_str_mv 10.1021/ic049255u
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title Preparation of 1-p-Halophenyl and 1-p-Biphenylyl Substituted Monocarbadodecaborate Anions [closo-1-Ar−CB11H11]- by Insertion of Arylhalocarbenes into [nido-B11H14]
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