Direct Imaging of Zero-Field Dipolar Structures in Colloidal Dispersions of Synthetic Magnetite

Magnetite (Fe3O4) forms the basis of most dispersions studied in the field of magnetic fluids and magnetic colloids. Despite extensive theory and simulations on chain formation in dipolar fluids in zero field, such structures have not yet been imaged in laboratory-made magnetite dispersions. Here, w...

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Published in:Journal of the American Chemical Society 2004-12, Vol.126 (51), p.16706-16707
Main Authors: Klokkenburg, Mark, Vonk, Chantal, Claesson, Eva M, Meeldijk, Johannes D, Erné, Ben H, Philipse, Albert P
Format: Article
Language:English
Subjects:
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Physical and chemical studies. Granulometry. Electrokinetic phenomena
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cited_by cdi_FETCH-LOGICAL-a447t-e8c8f57dd5cc7eb24eb543051da2971099e0c3f7047d89030574e1d3f45fe2a83
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container_end_page 16707
container_issue 51
container_start_page 16706
container_title Journal of the American Chemical Society
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creator Klokkenburg, Mark
Vonk, Chantal
Claesson, Eva M
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Philipse, Albert P
description Magnetite (Fe3O4) forms the basis of most dispersions studied in the field of magnetic fluids and magnetic colloids. Despite extensive theory and simulations on chain formation in dipolar fluids in zero field, such structures have not yet been imaged in laboratory-made magnetite dispersions. Here, we present the first direct observation of dipolar chain formation in zero field in a ferrofluid containing the largest synthetic single-domain magnetite particles studied so far. To our knowledge, this is the only ferrofluid system available at present that allows quantifying chain length and ring-size distributions of dipolar structures as a function of concentration and particle size.
doi_str_mv 10.1021/ja0456252
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Physical and chemical studies. Granulometry. Electrokinetic phenomena
title Direct Imaging of Zero-Field Dipolar Structures in Colloidal Dispersions of Synthetic Magnetite
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