Topochemical Limits for Solid-State Photoreactivity by Fine Tuning of the π−π Interactions

The limiting topochemical criteria for photodimerization were studied by modulation of the π−π stacking interactions between self-templating planar molecules with hydrogen bonding. The product yield and composition can be controlled predominantly by the distance between the reactive bonds.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2009-06, Vol.131 (21), p.7247-7249
Main Authors: Yang, Shi-Yao, Naumov, Panče, Fukuzumi, Shunichi
Format: Article
Language:English
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Summary:The limiting topochemical criteria for photodimerization were studied by modulation of the π−π stacking interactions between self-templating planar molecules with hydrogen bonding. The product yield and composition can be controlled predominantly by the distance between the reactive bonds.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja902094b