Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer

Wall decoration: Coordinatively unsaturated metal centers (CuII, CoII, and NiII) can be embedded in the pore wall of a microporous coordination polymer containing Schiff base type metalloligands [M(salphdc)]2− (H4salphdc=N,N′‐o‐phenylenebis(salicylideneimine‐5,5′‐dicarboxylic acid)). These coordinat...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2004-05, Vol.43 (20), p.2684-2687
Main Authors: Kitaura, Ryo, Onoyama, Goro, Sakamoto, Hirotoshi, Matsuda, Ryotaro, Noro, Sin-ichiro, Kitagawa, Susumu
Format: Article
Language:English
Subjects:
coordination polymers
crystal engineering
materials science
N,O ligands
O ligands
porous materials
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Summary:Wall decoration: Coordinatively unsaturated metal centers (CuII, CoII, and NiII) can be embedded in the pore wall of a microporous coordination polymer containing Schiff base type metalloligands [M(salphdc)]2− (H4salphdc=N,N′‐o‐phenylenebis(salicylideneimine‐5,5′‐dicarboxylic acid)). These coordination polymers possess large 1D channels with dimensions of approximately 14×14 Å2 (see structure).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200352596