Microhardness of resin cements in the intraradicular environment: Effects of water storage and softening treament

• Published in: Dental materials 2009-07, Vol.25 (7), p.868-876
• Main Authors: Pedreira, Ana Paula R.V, Pegoraro, Luiz Fernando, de Góes, Mario Fernando, Pegoraro, Thiago Amadei, Carvalho, Ricardo Marins
• Format: Article
• Language: English
• Subjects: Advanced Basic Science; Animals; Cattle; Composite Resins - chemistry; Dental Pulp Cavity - ultrastructure; Dentistry; Dual-cure resin cements; Ethanol - chemistry; Fiber posts; Hardness; Materials Testing; Microhardness; Post and Core Technique - instrumentation; Resin Cements - chemistry; Solvents - chemistry; Surface Properties; Temperature; Time Factors; Water - chemistry
• ISSN: 0109-5641; 1879-0097
• DOI: 10.1016/j.dental.2009.01.096

Abstract Objectives To analyze the microhardness of four dual-cure resin cements used for cementing fiber-reinforced posts under the following conditions: after 7 days of storage in water, after additional 24 h of immersion in 75% ethanol, and after 3 months of storage in water. Hardness measurements were taken at the cervical, middle and apical thirds along the cement line. Methods Root canals of 40 bovine incisors were prepared for post space. Fibrekor® glass fiber-reinforced posts (Jeneric/Pentron) of 1 mm in diameter were cemented using Panavia F 2.0 (Kuraray), Variolink (Ivoclar-Vivadent), Rely X Unicem (3M ESPE) or Duolink (Bisco) ( N = 10). After 7 days of water storage at 37 °C, half the sample ( N = 5) was longitudinally sectioned and the initial microhardness measured along the cement line from cervical to apex. These same samples were further immersed in 75% ethanol for 24 h and reassessed. The remaining half ( N = 5) was kept unsectioned in deionized water at 37 °C for 3 months, followed by sectioning and measuring. Data were analyzed by a series of two-way ANOVA and Tukey tests at α = 5%. Results Statistically significant differences were identified among the cements, thirds and conditions. Significant interactions were also observed between cements and thirds and between cements and conditions. Panavia F exhibited significantly higher initial microhardness than the other three cements, which showed no statistical difference among themselves. Variolink and Duolink showed significantly higher microhardness values in the cervical third, without significant difference among the thirds for the other cements. Immersion in ethanol significantly reduced the hardness values for all cements, regardless of the thirds. Storage in water for 3 months had no influence on the hardness of most of the cements, with the exception of Unicem that showed a significant increase in the hardness values after this period. Significance Results showed heterogeneity in the microhardness of the cements inside the canal. All cements presented some degree of softening after ethanol treatment, which suggests instability of the polymer. The quality of curing of resin cements in the root canal environment seems unpredictable and highly material dependent.