Synthetic Routes to Linear Oligo-Tröger's Bases

Derivatives of Tröger's base (TB) have played important roles in receptor construction due to their rigid V-shape. A new class of these compounds are the oligo-TBs, which can function as cavitands. Herein, we describe both stepwise and one-step (oligomerization) methods suitable for the prepara...

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Bibliographic Details
Published in:Organic letters 2005-01, Vol.7 (1), p.67-70
Main Authors: Dolenský, Bohumil, Valík, Martin, Sýkora, David, Král, Vladimír
Format: Article
Language:English
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Summary:Derivatives of Tröger's base (TB) have played important roles in receptor construction due to their rigid V-shape. A new class of these compounds are the oligo-TBs, which can function as cavitands. Herein, we describe both stepwise and one-step (oligomerization) methods suitable for the preparation of linear oligo-TBs.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol047902f