[μ-N, N'-Bis(2-aminoethyl)oxamidato(2-)]bis[(4,5-diazafluoren-9-one)-perchloratoc opper(II)] 4,5-diazafluoren-9-one disolvate

The title compound, [Cu2(C6)H12N4O2)(ClO4)2(C11H6N2O)2].-2C11H6N2O, contains a dinuclear copper(II) complex which lies about a twofold axis at the mid-point of the C-C bond of the oxamide ligand that bridges the two Cu(II) atoms. The Cu...Cu distance is 5.215 (2) A and the Cu atoms have distorted oc...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2005-01, Vol.61 (Pt 1), p.m7-m9
Main Authors: LI, Yan-Ping, YANG, Pin, HUANG, Zi-Xiang, XIE, Fu-Xin
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Crystalline state (including molecular motions in solids)
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory of crystal structure, crystal symmetry
calculations and modeling
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Summary:The title compound, [Cu2(C6)H12N4O2)(ClO4)2(C11H6N2O)2].-2C11H6N2O, contains a dinuclear copper(II) complex which lies about a twofold axis at the mid-point of the C-C bond of the oxamide ligand that bridges the two Cu(II) atoms. The Cu...Cu distance is 5.215 (2) A and the Cu atoms have distorted octahedral coordination geometry. Intramolecular N-H...O and N-H...N hydrogen bonds and intermolecular C-H...O hydrogen bonds, together with pi-pi stacking interactions, dominate throughout the crystal structure.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270104028367