New Thermal Source of Dimethoxycarbene Leading to Zwitterionic Intermediates and 2:1 Stoichiometry in Reaction with Electrophilic Alkenes

At 50 °C, dimethyl dicyanofumarate and maleate react with 2 equiv of dimethoxycarbene to generate the products shown.

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Bibliographic Details
Published in:Organic letters 2005-02, Vol.7 (3), p.487-489
Main Authors: Zhou, Hongwei, Mloston, Grzegorz, Warkentin, John
Format: Article
Language:English
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Description
Summary:At 50 °C, dimethyl dicyanofumarate and maleate react with 2 equiv of dimethoxycarbene to generate the products shown.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol040068+