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Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate
Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2(R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and...
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Published in: | Dalton transactions : an international journal of inorganic chemistry 2005-02 (3), p.421-423 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2(R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and also represent the first lanthanide borohydride complex for the polymerisation of methyl methacrylate. |
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ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/b417279p |