Temperature Dependence of the Primary Relaxation in 1-Hexyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide

• Published in: The journal of physical chemistry. B 2009-06, Vol.113 (25), p.8469-8474
• Main Authors: Russina, Olga, Beiner, Mario, Pappas, Catherine, Russina, Margarita, Arrighi, Valeria, Unruh, Tobias, Mullan, Claire L, Hardacre, Christopher, Triolo, Alessandro
• Format: Article
• Language: English
• Subjects: B: Macromolecules, Soft Matter
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp900142m

We present results from complementary characterizations of the primary relaxation rate of a room temperature ionic liquid (RTIL), 1-hexyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl} imide, [C6mim][Tf2N], over a wide temperature range. This extensive data set is successfully merged with existing literature data for conductivity, viscosity, and NMR diffusion coefficients thus providing, for the case of RTILs, a unique description of the primary process relaxation map over more than 12 decades in relaxation rate and between 185 and 430 K. This unique data set allows a detailed characterization of the VTF parameters for the primary process, that are: B = 890 K, T 0 = 155.2 K, leading to a fragility index m = 71, corresponding to an intermediate fragility. For the first time neutron spin echo data from a fully deuteriated sample of RTIL at the two main interference peaks, Q = 0.76 and 1.4 Å−1 are presented. At high temperature (T > 250 K), the collective structural relaxation rate follows the viscosity behavior; however at lower temperatures it deviates from the viscosity behavior, indicating the existence of a faster process.