Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes

Oxazole and thiazole molecules N-coordinated to manganese(i) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid-base reactions, and subsequently transmetalated to gold(i), via isolable heterometallic intermediates.

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2009-01 (19), p.2741-2743
Main Authors: Ruiz, Javier, Perandones, Bernabé F
Format: Article
Language:English
Subjects:
Isomerism
Magnetic Resonance Spectroscopy
Manganese - chemistry
Metals - pharmacology
Methane - analogs & derivatives
Methane - chemical synthesis
Organogold Compounds - chemical synthesis
Oxazoles - chemistry
Thiazoles - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Oxazole and thiazole molecules N-coordinated to manganese(i) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid-base reactions, and subsequently transmetalated to gold(i), via isolable heterometallic intermediates.
ISSN:1359-7345
1364-548X
DOI:10.1039/b900955h