A Rock-Salt-Like Lattice Structure Consisting of Monocationic and Monoanionic AuIAgICuII Supramolecular Cages of D-Penicillaminate

All three coinage metals are present in the supramolecular compound created from D‐penicillamine (D‐H2pen) by stepwise reaction with AuI, AgI, and CuII in the presence of Cl−. In this compound, 20‐nuclear monocationic [Au6Ag8Cu6Cl(H2O)5(D‐pen)12]+ and 21‐nuclear monoanionic [Au6Ag9Cu6Cl4(H2O)6(D‐pen...

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Published in:Angewandte Chemie International Edition 2005-02, Vol.44 (7), p.1088-1092
Main Authors: Toyota, Atsushi, Yamaguchi, Tadashi, Igashira-Kamiyama, Asako, Kawamoto, Tatsuya, Konno, Takumi
Format: Article
Language:English
Subjects:
aggregation
Antirheumatic Agents - chemistry
cage compounds
Chelating Agents - chemistry
Copper - chemistry
Gold Compounds - chemistry
Ions - chemistry
Models, Molecular
Molecular Structure
Penicillamine - chemistry
S ligands
Salts - chemistry
Silver Compounds - chemistry
supramolecular chemistry
transition metals
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container_issue 7
container_start_page 1088
container_title Angewandte Chemie International Edition
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creator Toyota, Atsushi
Yamaguchi, Tadashi
Igashira-Kamiyama, Asako
Kawamoto, Tatsuya
Konno, Takumi
description All three coinage metals are present in the supramolecular compound created from D‐penicillamine (D‐H2pen) by stepwise reaction with AuI, AgI, and CuII in the presence of Cl−. In this compound, 20‐nuclear monocationic [Au6Ag8Cu6Cl(H2O)5(D‐pen)12]+ and 21‐nuclear monoanionic [Au6Ag9Cu6Cl4(H2O)6(D‐pen)12]− (see picture) supramolecular cages, each of which accommodates a Cl− ion (green), are linked so as to form a giant rock‐salt‐like lattice structure.
doi_str_mv 10.1002/anie.200462205
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subjects aggregation
Antirheumatic Agents - chemistry
cage compounds
Chelating Agents - chemistry
Copper - chemistry
Gold Compounds - chemistry
Ions - chemistry
Models, Molecular
Molecular Structure
Penicillamine - chemistry
S ligands
Salts - chemistry
Silver Compounds - chemistry
supramolecular chemistry
transition metals
title A Rock-Salt-Like Lattice Structure Consisting of Monocationic and Monoanionic AuIAgICuII Supramolecular Cages of D-Penicillaminate
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