The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh-->B)(mt = methimazolyl)

The reaction of [Rh(C6H5)Cl2(PPh3)2] with Na[HB(mt)3](mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh-->B) the first authentic example of a compound with a rhodium-boron dative bond.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-01 (2), p.221-223
Main Authors: Crossley, Ian R, Foreman, Mark R St-J, Hill, Anthony F, White, Andrew J P, Williams, David J
Format: Article
Language:English
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Summary:The reaction of [Rh(C6H5)Cl2(PPh3)2] with Na[HB(mt)3](mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh-->B) the first authentic example of a compound with a rhodium-boron dative bond.
ISSN:1359-7345
1364-548X
DOI:10.1039/b413305f