Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-03 (11), p.1405-1407
Main Authors: Sastri, Chivukula V, Sook Seo, Mi, Joo Park, Mi, Mook Kim, Kwan, Nam, Wonwoo
Format: Article
Language:English
Subjects:
Hydrogen-Ion Concentration
Iron - chemistry
Nitrogen - chemistry
Nonheme Iron Proteins - chemistry
Oxidation-Reduction
Solutions - chemistry
Sulfides - chemistry
Water - chemistry
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Summary:A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.
ISSN:1359-7345
1364-548X
DOI:10.1039/b415507f