N,N′-Bis(2-ammonioethyl)propane-1,3-diaminium tris(perchlorate) chloride

The crystal structure of the title compound, C7H24N44+·3ClO4−·Cl−, is mainly determined by electrostatic interactions between the charged species and a number of relatively weak N—H...O and N—H...Cl− hydrogen bonds. The rich structure of such hydrogen bonds creates infinite layers of ions extending...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2009-08, Vol.65 (8), p.o371-o373
Main Authors: Szcześniak, Hanna B., Patroniak, Violetta, Radecka-Paryzek, Wanda, Kubicki, Maciej
Format: Article
Language:English
Subjects:
Chemical compounds
Crystal structure
Crystallography
Hydrogen bonds
Ions
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Summary:The crystal structure of the title compound, C7H24N44+·3ClO4−·Cl−, is mainly determined by electrostatic interactions between the charged species and a number of relatively weak N—H...O and N—H...Cl− hydrogen bonds. The rich structure of such hydrogen bonds creates infinite layers of ions extending along the [001] direction. The tetracation has the gttttttg conformation, similar to the single previously known example of such a cation. The presence of two different anions can be connected with the undecided competition between them, and some of the packing advantages of such a situation are found in the crystal structure.
ISSN:0108-2701
1600-5759
DOI:10.1107/S010827010902410X