A Heterometal Single-Molecule Magnet of [MnIII 2NiII 2Cl2(salpa)2]

The tetranuclear complex [MnIII 2NiII 2Cl2(salpa)2] (salpa = N-(2-hydroxybenzyl)-3-amino-1-propanol) has a spin ground state of S = 6 and was confirmed to be an SMM based on a steplike feature of the magnetization hysteresis loop at 0.55 K.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2005-04, Vol.127 (13), p.4568-4569
Main Authors: Oshio, Hiroki, Nihei, Masayuki, Koizumi, Satoshi, Shiga, Takuya, Nojiri, Hiroyuki, Nakano, Motohiro, Shirakawa, Naoki, Akatsu, Mitsuhiro
Format: Article
Language:English
Subjects:
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
Magnetic properties and materials
Molecular magnets
Physics
Studies of specific magnetic materials
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Description
Summary:The tetranuclear complex [MnIII 2NiII 2Cl2(salpa)2] (salpa = N-(2-hydroxybenzyl)-3-amino-1-propanol) has a spin ground state of S = 6 and was confirmed to be an SMM based on a steplike feature of the magnetization hysteresis loop at 0.55 K.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja042217p