Magnesium-Based 3D Metal−Organic Framework Exhibiting Hydrogen-Sorption Hysteresis

A new magnesium metal−organic framework (MOF) based on an asymmetrical ligand, biphenyl-3,4′,5-tricarboxylate (H3BPT), has been synthesized and structurally characterized. MOF Mg3(BPT)2(H2O)4 (1) consists of 1D hexagonal nanotube-like channels and exhibits pronounced hydrogen-sorption hysteresis at...

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Published in:Inorganic chemistry 2009-09, Vol.48 (17), p.8069-8071
Main Authors: Guo, Zhiyong, Li, Guanghua, Zhou, Liang, Su, Shenqqun, Lei, Yongqian, Dang, Song, Zhang, Hongjie
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description A new magnesium metal−organic framework (MOF) based on an asymmetrical ligand, biphenyl-3,4′,5-tricarboxylate (H3BPT), has been synthesized and structurally characterized. MOF Mg3(BPT)2(H2O)4 (1) consists of 1D hexagonal nanotube-like channels and exhibits pronounced hydrogen-sorption hysteresis at medium pressure.
doi_str_mv 10.1021/ic901056d
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title Magnesium-Based 3D Metal−Organic Framework Exhibiting Hydrogen-Sorption Hysteresis
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