A paramagnetic Cu(I)/Cu(II)/Zn(II) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization

A Cu(I)/Cu(II)/Zn(II) mixed-valent [Cu(en)2][Zn(NC)4(CuCN)2] polymer, which has a 2-D layer structure with six structurally inequivalent cyanides in four distinct bonding modes, has been prepared; structurally informative 13C and 15N MAS NMR spectra of this paramagnetic system are readily observable...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2006-02 (7), p.744-746
Main Authors: Ouyang, Liang, Aguiar, Pedro M, Batchelor, Raymond J, Kroeker, Scott, Leznoff, Daniel B
Format: Article
Language:English
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Summary:A Cu(I)/Cu(II)/Zn(II) mixed-valent [Cu(en)2][Zn(NC)4(CuCN)2] polymer, which has a 2-D layer structure with six structurally inequivalent cyanides in four distinct bonding modes, has been prepared; structurally informative 13C and 15N MAS NMR spectra of this paramagnetic system are readily observable.
ISSN:1359-7345
1364-548X
DOI:10.1039/b512430a