A pilot simulation study of arsenic tracked from CCA-treated decks onto carpets

• Published in: The Science of the total environment 2009-11, Vol.407 (22), p.5818-5824
• Main Authors: Patch, Steven C., Ullman, Margaret C., Maas, Richard P., Jetter, James J.
• Format: Article
• Language: English
• Subjects: Air. Soil. Water. Waste. Feeding; Applied sciences; Arsenates - analysis; Arsenic; Arsenic - analysis; arsenic concentration; arsenic transfer; Atmospheric pollution; Biological and medical sciences; Carpet; carpet dust; Carpets; CCA-treated lumber; chemical concentration; chromated copper arsenate; Decks; dry environmental conditions; Drying; Dust - analysis; Environment. Living conditions; environmental exposure; Exact sciences and technology; Floors and Floorcoverings; foot traffic; home furnishings; Indoor; indoor environmental quality; indoor exposure; Indoor pollution and occupational exposure; lumber; Medical sciences; Models, Chemical; pollutants; Pollution; preservative treated wood; preservative-treated decks; Public health. Hygiene; Public health. Hygiene-occupational medicine; shoe contamination; Shoes; simulated track-in; Simulation; Track-in; Traffic engineering; Traffic flow; walking; wet environmental conditions; Wood - chemistry; wood preservatives
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2009.07.022

A controlled simulation experiment was performed to assess whether dislodgeable arsenic can be tracked onto carpets via foot traffic from chromated copper arsenate (CCA) pressure-treated decks. The pilot simulation study demonstrated that it is possible to track arsenic from CCA-decks onto carpets under the test conditions evaluated. A total of nine CCA-decks and two non-CCA-treated control surfaces were tested under wet and dry conditions. Five participants walked in a controlled manner (60 cycles, 11 steps per cycle) across decks and then walked over various lanes of carpet to simulate the tracking of arsenic indoors on the bottoms of shoes under heavy foot traffic conditions. To determine if arsenic was transferred from the CCA-treated wood to the carpet via shoes, laboratory analysis was performed on three different types of samples: (1) wipe samples of dislodgeable arsenic from a 46 cm 2 area of carpet, (2) dust samples obtained from vacuuming a 7442 cm 2 area of carpet, and (3) extractions of 13 cm 2 carpet samples. Wipe samples were also taken directly from the deck lumber. Following digestion and extraction, the amount of arsenic in each sample was measured using Graphite Furnace Atomic Absorption Spectrometry. The mean arsenic concentration measured on the carpets was 2.52 μg/(100 cm 2) and 2.05 μg/(100 cm 2) with wipes for the dry and wet conditions, respectively, 4.69 μg/(100 cm 2) and 0.68 μg/(100 cm 2) with vacuumed dust for the dry and wet conditions, respectively, and 15.56 μg/(100 cm 2) and 12.31 μg/(100 cm 2) with carpet extractions for the dry and wet conditions, respectively. The mean arsenic concentration measured on the decks was 22.2 μg/(100 cm 2) with wipes. Further research is needed to determine if indoor exposure to arsenic due to track-in from outdoor decks via foot traffic is significant compared to exposures from other sources.