Planar Chiral Cyclic Amine and Its Derivatives:  Synthesis and Stereochemical Behavior

Nine-membered diallylic cyclic amines and amides have remarkably stable planar chirality. The transformation of enantiomerically enriched amides provides optically active nitrogen heterocycles containing stereogenic centers in a stereospecific fashion.

Saved in:
Bibliographic Details
Published in:Organic letters 2006-03, Vol.8 (5), p.963-965
Main Authors: Tomooka, Katsuhiko, Suzuki, Masaki, Shimada, Maki, Yanagitsuru, Syun-ichi, Uehara, Kazuhiro
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Nine-membered diallylic cyclic amines and amides have remarkably stable planar chirality. The transformation of enantiomerically enriched amides provides optically active nitrogen heterocycles containing stereogenic centers in a stereospecific fashion.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol053141k