Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand

From a theoretical prediction to an experimental finding: Oxidation of two bridging diphenylphosphanido ligands to a neutral tetraphenyldiphosphane is predicted theoretically and achieved experimentally in a trinuclear Pt2Pd complex (see scheme, RF=C6F5, P*=PPh2).

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2005-04, Vol.44 (16), p.2407-2410
Main Authors: Forniés, Juan, Fortuño, Consuelo, Ibáñez, Susana, Martín, Antonio, Tsipis, Athanasios C., Tsipis, Constantinos A.
Format: Article
Language:English
Subjects:
cluster compounds
density functional calculations
P ligands
palladium
platinum
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Summary:From a theoretical prediction to an experimental finding: Oxidation of two bridging diphenylphosphanido ligands to a neutral tetraphenyldiphosphane is predicted theoretically and achieved experimentally in a trinuclear Pt2Pd complex (see scheme, RF=C6F5, P*=PPh2).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200462498