Bromoiodinanes with an I(III)-Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

Bromoiodinanes--conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically--act as electrophilic bromine donors.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2006-01 (13), p.1442-1444
Main Authors: Braddock, D Christopher, Cansell, Gemma, Hermitage, Stephen A, White, Andrew J P
Format: Article
Language:English
Subjects:
Bromides - chemistry
Bromine - chemistry
Crystallography, X-Ray
Electrons
Iodine - chemistry
Models, Molecular
Molecular Structure
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Description
Summary:Bromoiodinanes--conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically--act as electrophilic bromine donors.
ISSN:1359-7345
1364-548X
DOI:10.1039/b600455e