Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidation by (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand

A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the CC bond and hydroxylation of THF by H-atom abstr...

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Published in:Journal of the American Chemical Society 2006-03, Vol.128 (12), p.3874-3875
Main Authors: Matsumoto, Takahiro, Furutachi, Hideki, Kobino, Masashi, Tomii, Masato, Nagatomo, Shigenori, Tosha, Takehiko, Osako, Takao, Fujinami, Shuhei, Itoh, Shinobu, Kitagawa, Teizo, Suzuki, Masatatsu
Format: Article
Language:English
Subjects:
Benzene Derivatives - chemistry
Copper - chemistry
Epoxy Compounds - chemistry
Hydroxylation
Kinetics
Ligands
Models, Molecular
Organometallic Compounds - chemistry
Pyridines - chemistry
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cited_by cdi_FETCH-LOGICAL-a266t-5cbb78e251c0e7e71b1ee4052b3263ac740d5e251a4d76e578d9ee337e01ea3
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container_title Journal of the American Chemical Society
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creator Matsumoto, Takahiro
Furutachi, Hideki
Kobino, Masashi
Tomii, Masato
Nagatomo, Shigenori
Tosha, Takehiko
Osako, Takao
Fujinami, Shuhei
Itoh, Shinobu
Kitagawa, Teizo
Suzuki, Masatatsu
description A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the CC bond and hydroxylation of THF by H-atom abstraction.
doi_str_mv 10.1021/ja058117g
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Benzene Derivatives - chemistry
Copper - chemistry
Epoxy Compounds - chemistry
Hydroxylation
Kinetics
Ligands
Models, Molecular
Organometallic Compounds - chemistry
Pyridines - chemistry
title Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidation by (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand
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