Cyclomaltooligosaccharide (cyclodextrin)-assisted enantiomeric recognition of benzo[ lmn][3,8]phenanthroline-derived amino acids

[Display omitted] Formation of self-assembly molecular aggregates and cyclomaltooligosaccharide (cyclodextrin) molecular aggregates with benzo[ lmn][3,8]phenanthroline-derived amino acids is presented. The nature of the molecular aggregates was studied by negative-ion electrospray-ionization mass sp...

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Bibliographic Details
Published in:Carbohydrate research 2005-05, Vol.340 (7), p.1413-1418
Main Authors: Jursic, Branko S., Patel, Paresh K.
Format: Article
Language:English
Subjects:
Amino Acids - chemistry
Cyclodextrin
Cyclodextrins - chemistry
Cyclomaltooligosaccharide
Electrospray-ionization mass spectrometry
Enantiomeric recognition
ESIMS
Isomerism
Molecular aggregation
Phenanthrolines - chemistry
Solutions - chemistry
Spectrometry, Mass, Electrospray Ionization
Water - chemistry
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Summary:[Display omitted] Formation of self-assembly molecular aggregates and cyclomaltooligosaccharide (cyclodextrin) molecular aggregates with benzo[ lmn][3,8]phenanthroline-derived amino acids is presented. The nature of the molecular aggregates was studied by negative-ion electrospray-ionization mass spectrometry (ESIMS). The enantiomeric recognition was demonstrated by NMR enantiomeric discrimination of the amino acid derivatives in aqueous solutions of cyclodextrins.
ISSN:0008-6215
1873-426X
DOI:10.1016/j.carres.2005.03.002