An Efficient Stereoselective Dihydroxylation of Glycals using a Bimetallic System, RuCl3/CeCl3/NaIO4

A catalytic dihydroxylation reaction on glycals has been developed using a bimetallic oxidizing system to furnish sugar 1,2-diols in a highly setreoselective manner.

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Bibliographic Details
Published in:Journal of organic chemistry 2006-03, Vol.71 (7), p.2911-2913
Main Authors: Tiwari, Pallavi, Misra, Anup Kumar
Format: Article
Language:English
Subjects:
Carbohydrate Conformation
Carbohydrate Sequence
Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides
Carbohydrates. Nucleosides and nucleotides
Catalysis
Catalysts: preparations and properties
Cesium - chemistry
Chemistry
Chlorides - chemistry
Exact sciences and technology
General and physical chemistry
Glycosides - chemical synthesis
Glycosides - chemistry
Hydroxylation
Iodates - chemistry
Molecular Sequence Data
Organic chemistry
Oxidation-Reduction
Preparations and properties
Ruthenium Compounds - chemistry
Sodium - chemistry
Stereoisomerism
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Description
Summary:A catalytic dihydroxylation reaction on glycals has been developed using a bimetallic oxidizing system to furnish sugar 1,2-diols in a highly setreoselective manner.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo0526385