Selective O2 oxidation of air-sensitive lanthanocene thiolates and thioether chelate

Two unusual regioselective O2 oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-05 (18), p.2342-2344
Main Authors: Zhou, Xigeng, Zhu, Ming, Zhang, Libei, Zhu, Zhenyu, Pi, Chengfu, Pang, Zhen, Weng, Linhong, Cai, Ruifang
Format: Article
Language:English
Subjects:
Air
Chelating Agents - chemistry
Crystallography, X-Ray
Lanthanoid Series Elements - chemistry
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Oxidation-Reduction
Oxygen - chemistry
Sensitivity and Specificity
Sulfhydryl Compounds - chemistry
Sulfides - chemistry
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Description
Summary:Two unusual regioselective O2 oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.
ISSN:1359-7345
1364-548X
DOI:10.1039/b417609j