2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG

Two 2D supramolecular structures of macrocycle 1 and 1/C60 have been obtained on HOPG by self-assembly under ambient conditions and investigated by high-resolution STM. The monolayers of 1 are characterized by structures with perfect ordering over relatively large areas. In the case of 1/C60, the si...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2006-04, Vol.128 (13), p.4218-4219
Main Authors: Pan, Ge-Bo, Cheng, Xiao-Hong, Höger, Sigurd, Freyland, Werner
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3
cites cdi_FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3
container_end_page 4219
container_issue 13
container_start_page 4218
container_title Journal of the American Chemical Society
container_volume 128
creator Pan, Ge-Bo
Cheng, Xiao-Hong
Höger, Sigurd
Freyland, Werner
description Two 2D supramolecular structures of macrocycle 1 and 1/C60 have been obtained on HOPG by self-assembly under ambient conditions and investigated by high-resolution STM. The monolayers of 1 are characterized by structures with perfect ordering over relatively large areas. In the case of 1/C60, the size of the macrocycle 1 and the presence of two individual bithiophene units per ring lead in the final superstructure to a 1:2 stoichiometry. The fullerenes are not trapped at the graphite surface inside the macrocyclic holes but are located around the periphery of the bithiophene units. This clearly shows that the donor−acceptor interaction between C60 and the electron-rich units of the ring is the dominant factor for the structure formation.
doi_str_mv 10.1021/ja060469f
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_67812938</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>67812938</sourcerecordid><originalsourceid>FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3</originalsourceid><addsrcrecordid>eNptkE1vEzEQhi1ERUPhwB9AvoDEYak_Ynv3iFLaIKVtpISzNfWO1Q2b9WKvBf33uErUXDiNZubRq5mHkA-cfeVM8MsdMM3muvGvyIwrwSrFhX5NZowxUZlay3PyNqVdaeei5m_IOddK100tZ8SLK7rJY4R96NHlHiLdTDG7KUdMNHgKdPMII1ZrjKlLEw4TvQUXg3tyPVIYWroIVYtjSN3UhYH-6aZHep37HiMOSMtkeb--eUfOPPQJ3x_rBfl5_X27WFar-5sfi2-rCmTNpwodSqbQNV4b2WotleGNN9zNNQhhGHoB3CjGXFs3jmH5WWn54DV4z1nj5AX5fMgdY_idMU123yWHfQ8DhpysNjUXjawL-OUAlldSiujtGLs9xCfLmX2Wal-kFvbjMTQ_7LE9kUeLBfh0BCA56H2EwXXpxJmGqYbrwlUH7lnk35c9xF_lMGmU3a43lq_Y8m67YFadcsEluws5DsXdfw78B5sZmWI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>67812938</pqid></control><display><type>article</type><title>2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Pan, Ge-Bo ; Cheng, Xiao-Hong ; Höger, Sigurd ; Freyland, Werner</creator><creatorcontrib>Pan, Ge-Bo ; Cheng, Xiao-Hong ; Höger, Sigurd ; Freyland, Werner</creatorcontrib><description>Two 2D supramolecular structures of macrocycle 1 and 1/C60 have been obtained on HOPG by self-assembly under ambient conditions and investigated by high-resolution STM. The monolayers of 1 are characterized by structures with perfect ordering over relatively large areas. In the case of 1/C60, the size of the macrocycle 1 and the presence of two individual bithiophene units per ring lead in the final superstructure to a 1:2 stoichiometry. The fullerenes are not trapped at the graphite surface inside the macrocyclic holes but are located around the periphery of the bithiophene units. This clearly shows that the donor−acceptor interaction between C60 and the electron-rich units of the ring is the dominant factor for the structure formation.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja060469f</identifier><identifier>PMID: 16568983</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Physics ; Structure and morphology; thickness ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; Thin film structure and morphology</subject><ispartof>Journal of the American Chemical Society, 2006-04, Vol.128 (13), p.4218-4219</ispartof><rights>Copyright © 2006 American Chemical Society</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3</citedby><cites>FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17905916$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16568983$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pan, Ge-Bo</creatorcontrib><creatorcontrib>Cheng, Xiao-Hong</creatorcontrib><creatorcontrib>Höger, Sigurd</creatorcontrib><creatorcontrib>Freyland, Werner</creatorcontrib><title>2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Two 2D supramolecular structures of macrocycle 1 and 1/C60 have been obtained on HOPG by self-assembly under ambient conditions and investigated by high-resolution STM. The monolayers of 1 are characterized by structures with perfect ordering over relatively large areas. In the case of 1/C60, the size of the macrocycle 1 and the presence of two individual bithiophene units per ring lead in the final superstructure to a 1:2 stoichiometry. The fullerenes are not trapped at the graphite surface inside the macrocyclic holes but are located around the periphery of the bithiophene units. This clearly shows that the donor−acceptor interaction between C60 and the electron-rich units of the ring is the dominant factor for the structure formation.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Structure and morphology; thickness</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>Thin film structure and morphology</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNptkE1vEzEQhi1ERUPhwB9AvoDEYak_Ynv3iFLaIKVtpISzNfWO1Q2b9WKvBf33uErUXDiNZubRq5mHkA-cfeVM8MsdMM3muvGvyIwrwSrFhX5NZowxUZlay3PyNqVdaeei5m_IOddK100tZ8SLK7rJY4R96NHlHiLdTDG7KUdMNHgKdPMII1ZrjKlLEw4TvQUXg3tyPVIYWroIVYtjSN3UhYH-6aZHep37HiMOSMtkeb--eUfOPPQJ3x_rBfl5_X27WFar-5sfi2-rCmTNpwodSqbQNV4b2WotleGNN9zNNQhhGHoB3CjGXFs3jmH5WWn54DV4z1nj5AX5fMgdY_idMU123yWHfQ8DhpysNjUXjawL-OUAlldSiujtGLs9xCfLmX2Wal-kFvbjMTQ_7LE9kUeLBfh0BCA56H2EwXXpxJmGqYbrwlUH7lnk35c9xF_lMGmU3a43lq_Y8m67YFadcsEluws5DsXdfw78B5sZmWI</recordid><startdate>20060405</startdate><enddate>20060405</enddate><creator>Pan, Ge-Bo</creator><creator>Cheng, Xiao-Hong</creator><creator>Höger, Sigurd</creator><creator>Freyland, Werner</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20060405</creationdate><title>2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG</title><author>Pan, Ge-Bo ; Cheng, Xiao-Hong ; Höger, Sigurd ; Freyland, Werner</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Structure and morphology; thickness</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>Thin film structure and morphology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pan, Ge-Bo</creatorcontrib><creatorcontrib>Cheng, Xiao-Hong</creatorcontrib><creatorcontrib>Höger, Sigurd</creatorcontrib><creatorcontrib>Freyland, Werner</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pan, Ge-Bo</au><au>Cheng, Xiao-Hong</au><au>Höger, Sigurd</au><au>Freyland, Werner</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2006-04-05</date><risdate>2006</risdate><volume>128</volume><issue>13</issue><spage>4218</spage><epage>4219</epage><pages>4218-4219</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Two 2D supramolecular structures of macrocycle 1 and 1/C60 have been obtained on HOPG by self-assembly under ambient conditions and investigated by high-resolution STM. The monolayers of 1 are characterized by structures with perfect ordering over relatively large areas. In the case of 1/C60, the size of the macrocycle 1 and the presence of two individual bithiophene units per ring lead in the final superstructure to a 1:2 stoichiometry. The fullerenes are not trapped at the graphite surface inside the macrocyclic holes but are located around the periphery of the bithiophene units. This clearly shows that the donor−acceptor interaction between C60 and the electron-rich units of the ring is the dominant factor for the structure formation.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>16568983</pmid><doi>10.1021/ja060469f</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0002-7863
ispartof Journal of the American Chemical Society, 2006-04, Vol.128 (13), p.4218-4219
issn 0002-7863
1520-5126
language eng
recordid cdi_proquest_miscellaneous_67812938
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title 2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T10%3A17%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=2D%20Supramolecular%20Structures%20of%20a%20Shape-Persistent%20Macrocycle%20and%20Co-deposition%20with%20Fullerene%20on%20HOPG&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Pan,%20Ge-Bo&rft.date=2006-04-05&rft.volume=128&rft.issue=13&rft.spage=4218&rft.epage=4219&rft.pages=4218-4219&rft.issn=0002-7863&rft.eissn=1520-5126&rft.coden=JACSAT&rft_id=info:doi/10.1021/ja060469f&rft_dat=%3Cproquest_cross%3E67812938%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a381t-ece305ec9f673d6635719f71c46a2270ef2a17500cd89c0e469563bf6aff109c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=67812938&rft_id=info:pmid/16568983&rfr_iscdi=true