Twist-grain-boundary structure in the B4 phase of a bent-core molecular system identified by second harmonic generation circular dichroism measurement

Second harmonic generation circular dichroism (SHG CD) measurements are performed on the B4 phase of a bent-core molecular system. Numerical analysis of SHG CD incorporating magnetic-dipole as well as electric-dipole interaction shows that the B4 phase is in a twist-grain-boundary structure with the...

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Bibliographic Details
Published in:Physical review letters 2005-04, Vol.94 (13), p.137801-137801
Main Authors: Araoka, Fumito, Ha, N Y, Kinoshita, Yoshitaka, Park, Byougchoo, Wu, J W, Takezoe, Hideo
Format: Article
Language:English
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Summary:Second harmonic generation circular dichroism (SHG CD) measurements are performed on the B4 phase of a bent-core molecular system. Numerical analysis of SHG CD incorporating magnetic-dipole as well as electric-dipole interaction shows that the B4 phase is in a twist-grain-boundary structure with the helical axis along the bent direction of the molecules. The result is extremely important in the sense that achiral molecules are spontaneously optically resolved, i.e., deracemization, the chiral domains of which give rise to huge chiral nonlinear optical effect.
ISSN:0031-9007
DOI:10.1103/PhysRevLett.94.137801