Pressure dependence of local structure in liquid carbon disulfide

High pressure x-ray diffraction measurements on liquid carbon disulfide up to 1.2 GPa are performed by using an energy dispersion method. The results are compared with a molecular dynamics calculation with usual Lennard-Jones potential. They give very good agreement for all pressures measured. It be...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 2006-04, Vol.124 (14), p.144511-144511-5
Main Authors: Yamamoto, Sekika, Ishibashi, Yasuhiko, Inamura, Yasuhiro, Katayama, Yoshinori, Mishina, Tomobumi, Nakahara, Jun'ichiro
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:High pressure x-ray diffraction measurements on liquid carbon disulfide up to 1.2 GPa are performed by using an energy dispersion method. The results are compared with a molecular dynamics calculation with usual Lennard-Jones potential. They give very good agreement for all pressures measured. It becomes clear that the liquid structure changes like hard core liquid up to the pressure just below crystallizing point. The relation between structural change and optical response at high pressure is discussed.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.2185094