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A Versatile and General One-Pot Method for Synthesizing Bis-spiroketal Motifs

A versatile and general method for the biomimetic construction of [5,5,5]- and [6,5,6]-bis-spiroketals, starting from easily accessible furan nuclei, by means of a powerful one-pot singlet oxygen-mediated cascade sequence is reported.

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Bibliographic Details
Published in:Organic letters 2006-04, Vol.8 (9), p.1945-1948
Main Authors: Georgiou, Thomas, Tofi, Maria, Montagnon, Tamsyn, Vassilikogiannakis, Georgios
Format: Article
Language:English
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Description
Summary:A versatile and general method for the biomimetic construction of [5,5,5]- and [6,5,6]-bis-spiroketals, starting from easily accessible furan nuclei, by means of a powerful one-pot singlet oxygen-mediated cascade sequence is reported.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol060558x