Iridium-Catalyzed Ring Cleavage Reaction of Cyclobutanone O-Benzoyloximes Providing Nitriles

Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes in the presence of 9,10-dihydroanthracene and potassium carbonate proceeds to give saturated nitriles via C−C bond fission at the sterically more hindered site.

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Published in:Organic letters 2005-06, Vol.7 (12), p.2425-2427
Main Authors: Nishimura, Takahiro, Yoshinaka, Tomoaki, Nishiguchi, Yoshiki, Maeda, Yasunari, Uemura, Sakae
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Language:English
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cited_by cdi_FETCH-LOGICAL-a379t-358fac158ef69081d23ecb541e0c17e1aea26f3c2e2fc59ee71eadc63e09b32e3
cites cdi_FETCH-LOGICAL-a379t-358fac158ef69081d23ecb541e0c17e1aea26f3c2e2fc59ee71eadc63e09b32e3
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container_issue 12
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container_title Organic letters
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creator Nishimura, Takahiro
Yoshinaka, Tomoaki
Nishiguchi, Yoshiki
Maeda, Yasunari
Uemura, Sakae
description Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes in the presence of 9,10-dihydroanthracene and potassium carbonate proceeds to give saturated nitriles via C−C bond fission at the sterically more hindered site.
doi_str_mv 10.1021/ol0507120
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title Iridium-Catalyzed Ring Cleavage Reaction of Cyclobutanone O-Benzoyloximes Providing Nitriles
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