Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water

L-glutamate and L-aspartate selectivity is achieved by the action of two Cu2+ metal ions rightly disposed in a cyclophane-type macrocyclic framework; electrochemical sensing of glutamate has been achieved by adsorption of the copper complexes on graphite electrodes.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-01 (24), p.3086-3088
Main Authors: Verdejo, Begoña, Aguilar, Juan, Doménech, Antonio, Miranda, Carlos, Navarro, Pilar, Jiménez, Hermás R, Soriano, Conxa, García-España, Enrique
Format: Article
Language:English
Subjects:
Aspartic Acid - analysis
Copper
Electrochemistry
Glutamic Acid - analysis
Organometallic Compounds - chemistry
Water
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Description
Summary:L-glutamate and L-aspartate selectivity is achieved by the action of two Cu2+ metal ions rightly disposed in a cyclophane-type macrocyclic framework; electrochemical sensing of glutamate has been achieved by adsorption of the copper complexes on graphite electrodes.
ISSN:1359-7345
1364-548X
DOI:10.1039/b503417e