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The synthesis of head-to-tail (H-T) dimers of 3-substituted thiophenes by the hypervalent iodine(III)-induced oxidative biaryl coupling reaction

The head-to-tail (H-T) dimers could be obtained selectively by the oxidative coupling reaction of 3-substituted thiophenes using a combination of hypervalent iodine(III) reagents and trimethylsilyl trifluoromethanesulfonate.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-06 (23), p.2930-2932
Main Authors: Dohi, Toshifumi, Morimoto, Koji, Kiyono, Yorito, Maruyama, Akinobu, Tohma, Hirofumi, Kita, Yasuyuki
Format: Article
Language:English
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Description
Summary:The head-to-tail (H-T) dimers could be obtained selectively by the oxidative coupling reaction of 3-substituted thiophenes using a combination of hypervalent iodine(III) reagents and trimethylsilyl trifluoromethanesulfonate.
ISSN:1359-7345
1364-548X
DOI:10.1039/b503058g