γ-Modification of poly[(N,N-diethyl­dithio­carbamato)silver(I)]

In the title compound, catena‐poly[[tri­silver(I)‐tri‐μ3‐N,N‐diethyl­dithio­carbamato‐3′κS:1κS′:2κS;1κS:2κS′:3κS;2κS:3κ2S,S′:1′κS′], [Ag3(C5H10NS2)3]n, the trigonally and tetra­hedrally coordinated Ag atoms are μ3‐bridged by κ3‐ and κ4‐S2CNEt2 ligands to form a ribbon structure along the c axis. The...

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Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-05, Vol.62 (5), p.m214-m216
Main Authors: Yu, Zhan, Song, Yan-Wei, Zhang, Qian-Feng
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Language:English
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Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Song, Yan-Wei
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description In the title compound, catena‐poly[[tri­silver(I)‐tri‐μ3‐N,N‐diethyl­dithio­carbamato‐3′κS:1κS′:2κS;1κS:2κS′:3κS;2κS:3κ2S,S′:1′κS′], [Ag3(C5H10NS2)3]n, the trigonally and tetra­hedrally coordinated Ag atoms are μ3‐bridged by κ3‐ and κ4‐S2CNEt2 ligands to form a ribbon structure along the c axis. There is a twofold axis parallel to the b axis and passing through the tetra­hedrally coordinated Ag atom. The S2CNEt2 ligands coordinate the Ag atoms in η1,η2‐ and η2,η2‐fashions, depending on the bridging S atoms. The distances between the trigonal Ag and S atoms are 2.4915 (11)–2.6205 (11) Å, while those between the tetra­hedral Ag and S atoms are 2.5457 (11) and 2.7145 (10) Å. The shortest Ag⋯Ag distance between trigonal Ag atoms is 2.8336 (7) Å, which indicates a weak Ag⋯Ag inter­action, whereas the shortest distance between trigonal and tetra­hedral Ag atoms is 3.463 (6) Å, which is considered as non‐bonding.
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Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Zhan</au><au>Song, Yan-Wei</au><au>Zhang, Qian-Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>γ-Modification of poly[(N,N-diethyl­dithio­carbamato)silver(I)]</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2006-05</date><risdate>2006</risdate><volume>62</volume><issue>5</issue><spage>m214</spage><epage>m216</epage><pages>m214-m216</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><coden>ACSCEE</coden><abstract>In the title compound, catena‐poly[[tri­silver(I)‐tri‐μ3‐N,N‐diethyl­dithio­carbamato‐3′κS:1κS′:2κS;1κS:2κS′:3κS;2κS:3κ2S,S′:1′κS′], [Ag3(C5H10NS2)3]n, the trigonally and tetra­hedrally coordinated Ag atoms are μ3‐bridged by κ3‐ and κ4‐S2CNEt2 ligands to form a ribbon structure along the c axis. There is a twofold axis parallel to the b axis and passing through the tetra­hedrally coordinated Ag atom. The S2CNEt2 ligands coordinate the Ag atoms in η1,η2‐ and η2,η2‐fashions, depending on the bridging S atoms. The distances between the trigonal Ag and S atoms are 2.4915 (11)–2.6205 (11) Å, while those between the tetra­hedral Ag and S atoms are 2.5457 (11) and 2.7145 (10) Å. The shortest Ag⋯Ag distance between trigonal Ag atoms is 2.8336 (7) Å, which indicates a weak Ag⋯Ag inter­action, whereas the shortest distance between trigonal and tetra­hedral Ag atoms is 3.463 (6) Å, which is considered as non‐bonding.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Blackwell Publishing Ltd</pub><pmid>16679587</pmid><doi>10.1107/S0108270106006688</doi></addata></record>
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subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title γ-Modification of poly[(N,N-diethyl­dithio­carbamato)silver(I)]
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