Captured and Cross-Linked Palladium Nanoparticles

Polystyrene−poly(ethylene glycol) resin-captured cross-linked palladium nanopaticles were prepared via a straightforward route, and their heterogeneous behavior was truly confirmed by various tests. They were applied to aqueous Suzuki cross-coupling reactions with various aryl bromides and recycled...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2006-05, Vol.128 (19), p.6276-6277
Main Authors: Cho, Jin Ku, Najman, Romain, Dean, Tony W, Ichihara, Osamu, Muller, Christophe, Bradley, Mark
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Chemistry
Conservation of Natural Resources
Cross-Linking Reagents
Exact sciences and technology
General and physical chemistry
Nanoparticles - chemistry
Palladium - chemistry
Polyethylene Glycols
Polystyrenes
Resins, Synthetic
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:Polystyrene−poly(ethylene glycol) resin-captured cross-linked palladium nanopaticles were prepared via a straightforward route, and their heterogeneous behavior was truly confirmed by various tests. They were applied to aqueous Suzuki cross-coupling reactions with various aryl bromides and recycled up to six times without loss of activity.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja057480k